Nitrite
Nitrogen compound (NO₂⁻) produced when ammonia-eating bacteria break down ammonia. Toxic to fish; converted to less-toxic nitrate by a second bacterial group. In a cycled tank, nitrite should read 0.
Nitrite is the middle stage of the nitrogen cycle. It's produced from ammonia by Nitrosomonas bacteria and consumed by Nitrobacter / Nitrospira bacteria. During fishless cycling, nitrite typically appears 1-2 weeks after ammonia and lingers until the nitrite-eating bacteria catch up.
Nitrite poisoning damages fish gills and impairs oxygen transport (it binds hemoglobin, causing 'brown blood disease'). Symptoms: gasping at the surface, lethargy, rapid gill movement.
Adding chloride competes with nitrite at the gill chloride channels — the chloride:nitrite protection mechanism documented in aquaculture literature. Conservative beginner-safe dose for a stopgap during a freshwater nitrite spike: plain aquarium salt at 1 tsp per 5 gallons. Skip salt or halve the dose if your tank has salt-sensitive species (corydoras and other scaleless catfish, kuhli loaches, freshwater shrimp/snails) or live plants that won't tolerate added chloride. Long-term solution is finishing the cycle.
Beginner-safe rule
Beginner-safe rule: if nitrite reads above 0.25 ppm, do a partial water change to dilute it. If you have fish in the tank and no salt-sensitive species, dose plain aquarium salt at 1 tsp per 5 gallons as a temporary protective measure. Don't stop dosing ammonia mid-cycle just because nitrite spikes — that stalls the cycle.
See also